徐小鹏:特聘研究员
研究方向:有机光电能源材料与器件
e-mail: xpxu@scu.edu.cn
教育经历:
2009.09-2013.06,黑龙江科技大学应用化学专业,理学学士
2013.09-2016.06,四川大学有机化学专业,理学硕士
2016.09-2019.06,四川大学有机化学专业,理学博士
工作及研究经历:
2019.07-2020.08,香港科技大学化学系,博士后
2020.09-至今,四川大学化学工程学院,特聘研究员
主要研究成果:
1.开发了一系列多氮杂环给体-受体型共轭聚合物给体材料,通过原子工程、侧链工程,硫化侧链、卤化策略等对材料的光物理性质进行精细调控,所构建的新型宽带隙给体材料在非富勒烯有机太阳能电池单层器件、叠层器件以及三元共混器件中均获得了较高的器件效率,处于国际领先水平;
2.深入开展了有机太阳能电池无卤溶剂制备工艺研究,通过材料和器件工艺的协同调控,显著提高了无卤溶剂制备的有机太阳能电池的器件性能。其中,所开发的溶剂老化(溶剂延迟)处理工艺刷新了无卤溶剂制备的有机太阳能电池光电转换效率记录;
3.开发了有机金属络合作用调控有机太阳能电池活性层形貌的新工艺,显著提高了有机太阳能电池的光电转换效率,并阐明了其形貌优化机理,所发表的成果入选esi热点高被引论文;
4.近年来,在energy environ sci., adv. mater., acs energy lett., adv. funct. mater., nano energy等国内外著名期刊上发表sci论文70余篇,影响因子大于10的有30余篇,大于5的有40余篇,被他人引用超过2800余次,其中,7篇单篇超过100余次,10余篇入选esi高被引论文和esi热点论文,授权中国发明专利2项。
代表性成果:
学术论文清单
2020年度
1. xiaopeng xu, liyang yu, he yan,* ruipeng li, qiang peng.* highly efficient non-fullerene organic solar cells enabled by a delayed processing method using a non-halogenated solvent.energy environ. sci.2020, 10.1039/d0ee02034f. (if = 30.289)
2. xiaopeng xu, kui feng, liyang yu, he yan,*ruipengli, and qiang peng.* highly efficient all-polymer solar cells enabled by p-doping of the polymer donor.acs energy lett.2020,5, 2434-2443. (if = 19.003)
3. xiaopeng xu, kui feng, young woong lee, hanyoungwoo,* guangjun zhang, and qiang peng.* subtle polymer donor and molecular acceptor design enable efficient polymer solar cells with a very small energy loss.adv. funct. mater.2020,20, 1907570. (if =16.836)
4. xiaopeng xu, young woong lee, han youngwoo* ying li, and qiang peng.* developing wide bandgap polymers based on solely benzodithiophene units for efficient polymer solar cells.chem. eur. j.2020, 26,11241-11249..(if = 4.857)
5. xiaopeng xu,ying li, qiang peng,* recentadvancesin morphology optimizations towards highly efficient ternary organic solar cells.nano select.2020,1, 30-58.
6. xiaopeng xu,ying li, qiang peng.* recent advances toward highly efficient tandem organic solar cells.small struct.2020, 2000016.
7. xiaopeng xu, liyang yu, qiang peng.* recent advances of wide bandgap polymer donors and their applications in organic solar cells.chin. j. chem. accepted.
8. xiaopeng xu, shiyang li, ying li, qiang peng.* recent progress in 4-anisylamino derivatives end-capped hole transporting materials for high performance perovskite solar cells.rare metals.2020. accepted.
9. shi-sheng wan,xiaopeng xu(co-first author), zhao jiang, jian yuan, asif mahmood, gui-zhou yuan, kai-kai liu, wei ma,* qiang peng * and jin-liang wang.* a bromine and chlorine concurrently functionalized end group for benzo[1,2-b:4,5-b']diselenophene-based nonfluorinated acceptors: new hybrid strategy to balance the crystallinity and miscibility of blend films enabling highly efficient polymer solar cells.j. mater. chem. a2020,8, 4856.(if = 11.301)
10. min deng,xiaopeng xu(co-first author), liyang yu,* ruipeng li, and qiang peng.* fused ring non-fullerene acceptors with benzothiophene dioxide end groups and their side chain effect investigations.dyes pigments2020,180, 108452. (if = 4.613)
11. min deng,xiaopeng xu, young woong lee, leif k. e. ericsson, ellen moons, han young woo,* ying li, liyang yu,* qiang peng.* fine regulation of crystallisation tendency to optimize the bhj nanostructure and performance of polymer solar cell.nanoscale2020,12, 12928-12941. (if = 6.880)
12. ziye tang,xiaopeng xu, ruipeng li,* liyang yu, lei meng,* yuliang wang,* ying li, and qiang peng.* asymmetric siloxane functional side chains enable high-performance donor copolymers for photovoltaic applications.acs appl. mater. interfaces2020,12, 17760. (if = 8.758)
13. zuoji liu, chengjia bao,xiaopeng xu, gangtie lei,* huishan gao, qiang peng,* and yu liu.* tuning terminal units to improve the photovoltaic performance of small molecules based on a large planar fused-ring core in solution-processed organic solar cells.org. electron.2020,78, 105566. (if = 3.310)
14. ying li, yufei gong, yongjie che,xiaopeng xu, liyang yu,* qiang peng*. propeller-like all-fused perylene diimide based electron acceptors with chalcogen linkage for efficient polymer solar cells.front. chem.2020,8, 350.
15. kai chen,* ruijie ma, tao liu,* zhenghui luo,xiaopeng xu, qiutang wang, yuzhong chen, yiqun xiao, xinhui lu, he yan,* fluorinated pyrazine-based d-a conjugated polymers for efficient non-fullerene polymer solar cells.j. mater. chem. a2020,8, 7083.(if = 11.301).
2019年度
1. xiaopeng xu, guangjun, zhang, liyang yu,* ruipeng, li, and qiang peng.* p3ht-based polymer solar cells with 8.25% efficiency enabled by a matched molecular acceptor and smart green-solvent processing technology.adv. mater.2019, 1906045.(if = 27.398,highlighted by material views china、高分子科技和cbg资讯)
2. xiaopeng xu, kui feng, zhaozhao bi, wei ma,* guangjun zhang, qiang peng.* single-junction polymer solar cells with 16.35% efficiency enabled by a platinum(ⅱ) complexation strategy.adv. mater.2019, 31, 1901872. (if = 27.398, highlighted by能源学人、中国聚合物网和x-mol资讯)
3. xiaopeng xu, min deng, young woong lee, han young woo,* xinhui, zou, yu jiang, liyang yu,* ying li, qiang peng.* realizing high-efficiency multiple blend polymer solar cells via a unique parallel-series working mechanism.j. mater. chem. a2019,7, 24937. (if = 11.301)
4. xiaopeng xu, zhaozhao bi, wei ma,* guangjun zhang, he yan,* ying li,a and qiang peng.* stable large area organic solar cells realized by using random terpolymer donors combining with ternary blend strategy.j. mater. chem. a2019, 7, 14199. (if = 11.301)
5. xiaopeng xu, guangjun zhang, ying li, and qiang peng.* the recent progress of wide bandgap donor polymers towards non-fullerene organic solar cells.chin. chem. lett.2019,30, 809.(if = 4.632)
6. guangjunzhang,xiaopeng xu (co-first author), young woong lee, han young woo,* ying li, qiang peng.* achieving high fill factor and stability in perylene diimide-based polymer solar cells by molecular lock effect between 4,4'-bipyridine and tri(8-hydroxyquinoline)aluminum(ⅲ) core.adv. funct. mater.2019, 29, 1902079.(if =16.836)
7. shi-shengwan,xiaopeng xu (co-first author), jin-liang wang,* gui-zhou yuan, zhao jiang, gao-yang ge, hai-rui bai, zheng li, qiang peng.* benzo[1,2-b:4,5-b']diselenophene-fused nonfullerene acceptors with alternative aromatic ring-based and monochlorinated end group: new synergistic strategy to simultaneously achieve highly efficient organic solar cells with energy loss of 0.49 ev.j. mater. chem. a2019,7, 11802.(if = 11.301)
8. guangjun zhang, jirui feng,xiaopeng xu(co-first author), wei ma,* ying li, and qiang peng.* perylene diimide‐based nonfullerene polymer solar cells with over 11% efficiency fabricated by smart molecular design and supramolecular morphology optimization.adv. funct. mater.2019,29, 1906587.(if =16.836)
9. kai-kai liu,xiaopeng xu(co-first author), jin-liang wang,* chao zhang, gao-yang ge, fang-dong zhuang, han-jian zhang, can yang, qiang peng* and jian pei. achieving high-performance non-halogenated nonfullerene acceptors-based organic solar cells with 13.7% efficiency through synergistic strategy of indacenodithieno[3,2-b]selenophene core unit and non-halogenated thiophene-based terminal group.j. mater. chem. a2019,7, 24389.(if = 11.301)
10. venkateshpiradi,xiaopeng xu (co-first author), zaiyu wang, jazib ali, qiang peng, feng liu, and xunjin zhu.* panchromatic ternary organic solar cells with porphyrin dimers and absorption-complementary benzodithiophene-based small molecules.acs appl. mater. interfaces2019, 11, 6283.(if = 8.758)
11. shan-shan ni,xiaopeng xu(co-first author), jin-liang wang,* shi-sheng wan, kai-kai liu, hai-rui bai, can yang, guiqin lv,* and qiang peng.* regioisomer-free chlorinated thiophene-based ending group for thieno[3,2-b]thiophene central unit-based acceptor enabling highly efficient nonfullerene polymer solar cells with highvocsimultaneously.solar rrl2019,4, 1900446. (if = 7.527)
12. min deng,xiaopengxu, young woo lee, han young woo, zhaohzao bi, wei ma, ying li,qiang peng.*dithienothiapyran: an excellent donor block for building high-performance copolymers in non-fullerene polymer solar cells.acs appl. mater. interfaces2019,11, 3308. (if = 8.758)
13. hang yin, song chen, pengqing bi,xiaopeng xu, sin hang cheung, xiaotao hao, qiang peng, * xunjin zhu, * shu kongso.* rationalizing device performance of perylenediimide derivatives as acceptors for bulk-heterojunction organic solar cells.org. electron.2019,65, 156.(if = 3.310)
14. shichao wang, zuojia li,xiaopeng xu, guangjun zhang, ying li, qiang peng.* amino-functionalized graphene quantum dots as cathode interlayer for efficient organic solar cells: quantum dot size on interfacial modification ability and photovoltaic performance.adv. mater. interfaces2019,6, 1801480. (if = 4.948)
15. chentong liao,mingzhang,xiaopeng xu, feng liu, ying li,qiang peng.*green solvent-processed efficient non-fullerene organic solar cells enabled by low-bandgap copolymer donors with edot side chains.j. mater. chem. a2019,7, 716.(if = 11.301)
16. kui feng, jun yuan, zhaozhao bi, wei ma,xiaopeng xu,guangjun zhang, qiang peng.* low-energy-loss polymer solar cells with 14.52% efficiency enabled by wide-band-gap copolymers.iscience2019,12, 1. (if = 4.447)
2018年度
1. xiaopeng xu, zuojia li, zhaozhao bi, ting yu, wei ma,* kui feng, ying li, and qiang peng.* highly efficient nonfullerene polymer solar cells enabled by a copper(i) coordination strategy employing an 1,3,4-oxadiazole-containing wide-bandgap copolymer donor.adv. mater.2018,30, 1800737. (if = 27.398)
2. xiaopeng xu,ting yu, zhaozhao bi, weima,* ying li, and qiang peng.* realizing over 13% efficiency in green-solvent-processed nonfullerene organic solar cells enabled by 1,3,4-thiadiazole-based wide-bandgap copolymers.adv. mater.2018,30, 1703973. (if = 27.398, esi highly cited paper; 2017年12月adv. mater.热点文章排行榜top10; highlighted by material views china、材料人、材料牛、搜狐媒体;2018年中国百篇最具影响国际学术论文)
3. quanquan zhang,xiaopeng xu (co-first author), song chen, govardhana babu bodedla, mingzi sun, qin hu, qiang peng,*bolonghuang, hanzhong ke,* feng liu,* thomas p. russell and xunjin zhu.* phenylene-bridged perylenediimide-porphyrin acceptors for non-fullerene organic solar cells.sustain. energy fuels2018,2, 2616. (if = 5.503)
4. guangjunzhang,xiaopeng xu, zhaozhao bi, wei ma, dongsheng tang, ying li,qiang peng.*fluorinated and alkylthiolated polymeric donors enable both efficient fullerene and nonfullerene polymer solar cells.adv. funct. mater.2018,28, 1706404.(if =16.836)
5. weiyun bai,xiaopeng xu, qingya li, yunxiang xu,* and qiang peng.* efficient nonfullerene polymer solar cells enabled by small-molecular acceptors with a decreased fused-ring core.small meth.2018,2, 1700373. (if = 12.130)
6. zuojia li,xiaopeng xu, guangjun zhang, ting yu, ying li, and qiang peng.* highly efficient non-fullerene polymer solar cells enabled by wide bandgap copolymers with conjugated selenyl side chains.solar rrl2018,2, 1800186. (if = 7.527)
7. zuojia li,xiaopeng xu, guangjun zhang, min deng, ying li,qiang peng*tris(8-hydroxyquinoline)aluminum(iii)-cored molecular cathode interlayer: improving electron mobility and photovoltaic efficiency of polymer solar cells.solar rrl2018,2, 1800182. (if = 7.527)
8. zhongbin qiu,xiaopeng xu, liang yang, yong pei, mengbin zhu,qiang peng,*yu liu.*tuning the central donor core viaintramolecularnoncovalent interactions based on d(a-ar)2type small molecules for high performance organic solar cells.solar energy2018,161, 138. (if = 4.608)
9. kui feng, guofang yang,xiaopeng xu, guangjun zhang, he yan, omar awartani, long ye, harald ade, ying li,qiang peng.*high-performance wide bandgap copolymers using an edot modified benzodithiophene donor block with 10.11% efficiency.adv. energy mater.2018,8, 1602773. (if = 25.245)
10. wenling wu, guangjun zhang,xiaopeng xu, shichao wang, ying li,qiang peng.*wide bandgap molecular acceptors with a truxene core for efficient nonfullerene polymer solar cells: linkage position on molecular configuration and photovoltaic properties.adv. funct. mater.2018,28, 1707493.(if =16.836)
11. dongshengtang, jiahui wan,xiaopeng xu, young woong lee, han young woo,*kui feng,qiang peng.*naphthobistriazole-based wide bandgap donor polymers for efficient non-fullerene organic solar cells: significant fine-tuning absorption and energy level by backbone fluorination.nano energy2018,53, 258. (if = 16.602)
12. zi shuai wang, xingang ren,xiaopeng xu,qiang peng,*wei e. i. sha, wallace c. h. choy. a comprehensively theoretical and experimental study of carrier generation and transport for achieving high performance ternary blend organic solar cells.nano energy2018,51, 206. (if = 16.602)
13. shichao wang, zuojia li,xiaopeng xu, meiling zhang, guangjun zhang, ying li andqiang peng.*self-doping small molecular conjugated electrolytes enabled by n-type side chains for highly efficient non-fullerene polymer solar cells.j mater. chem. a2018,6, 22503.(if = 11.301)
14. zuojia li, dongsheng tang, zhenkai ji, wei zhang,*xiaopeng xu, kui feng, ying li, and qiang peng.* highly efficient polymer solar cells via multiple cascade energy level engineering.j. mater. chem. c2018,6, 9119. (if = 7.059)
2017年度
1. xiaopeng xu, zhaozhao bi, wei ma,* zishuai wang, wallace c. h. choy,* wenlin wu, guangjun zhang, ying li, and qiang peng.* highly efficient ternary-blend polymer solar cells enabled by a nonfullerene acceptor and two polymer donors with a broad composition tolerance.adv. mater.2017,29, 1470271. (if = 27.398)
2. xiaopeng xu, guangjun zhang, yunzhe zhao, jiang liu, ying li, qiang peng.* highly efficient random terpolymers for photovoltaic applications with enhanced absorption and molecular aggregation.chin. j. polym. sci.,2017,35, 249. (if = 3.154)
3. xiaopeng xu, zuojia li, guangjun zhang, ying li, and qiang peng.* applications of naphthobisthiadiazole and its fused-ring acceptor units in polymer solar cells.polym. bull.2017,10, 64. (if = 2.014)
4. jiahui wan,xiaopeng xu (co-first author), guangjun zhang, ying li, kui feng, and qiang peng.* highly efficienthalogen-free solvent processed small-molecule organic solar cells enabled by material design and device engineering.energy environ. sci.2017,10, 1739.(if = 30.289)
5. ting yu,xiaopeng xu (co-first author), guangjun zhang, jiahui wan, ying li, and qiang peng.* wide bandgapcopolymersbased on quinoxalino[6,5-f]quinoxaline for highly efficient nonfullerene polymer solar cells.adv. funct. mater.2017,27, 1701491.(if =16.836)
6. zhenkai ji,xiaopeng xu (co-first author), guangjun zhang, ying li, and qiang peng.* synergistic effect of halogenation on molecular energy level and photovoltaic performance modulations of highly efficient small molecularmaterials.nano energy2017,40, 214.(if = 16.602)
7. yuwei duan,xiaopeng xu, he yan,* wenlin wu, zuojia li, and qiang peng.* pronounced effects of a triazine core on photovoltaic performance-efficient organic solar cells enabled by a pdi trimer-based small molecular acceptor.adv. mater.2017,29, 1605115. (if = 27.398)
8. ting yu,xiaopeng xu, ying li,* zuojia li, and qiang peng.* side-chain influence of wide-bandgap copolymers based on naphtho[1,2-b:5,6-b]bispyrazine and benzo[1,2-b:4,5-b']dithiophene for efficient photovoltaic applications.acs appl. mater. interfaces2017,9, 18142. (if = 8.758)
9. zhenguo wang,xiaopeng xu, zuojia li, kui feng, kai li, ying li,qiang peng.*solution-processed organic solar cells with 9.8% efficiency based on a new small molecule containing a 2d fluorinated benzodithiophene central unit.adv electron mater2016,2, 1600061. (if = 6.593)
10. yuwei duan,xiaopeng xu, ying li, zuojia li, and qiang peng*. chalcogen-atom-annulated perylene diimide trimers for highly efficient nonfullerene polymer solar cells.macromol. rapid commun.2017,38, 1700405. (if = 4.886)
11. zhongbin qiu,xiaopeng xu, shuai zhang, pu wang, yafei wang, yong pei,qiang peng,*yu liu. efficient strategies to improve photovoltaic performance of a-d-a type small molecules by introducing rigidly fluorinated central cores.dyes pigments2017,147, 505. (if = 4.613)
12. yuwei duan,xiaopeng xu, ying li,qiang peng.*recent development of perylene diimide-based small molecular non-fullerene acceptors in organic solar cells.chin. chem. lett.2017,28, 2105. (if = 4.632)
13. hongrui qi,xiaopeng xu, qiang tao, youming zhang, mengbing zhu, lin shao, weiguo zhu,*qiang peng,*yunfeng liao.*improving photovoltaic performance of the linear benzothienoindole-terminated molecules by tuning molecular framework and substituted position of terminals.dyes pigments2017,142, 406. (if = 4.613)
14. guangjun zhang, guofang yang, he yan,* joo-hyun kim, harald ade,* wenlin wu,xiaopeng xu, yuwei duan, and qiang peng* efficient nonfullerene polymer solar cells enabled by a novel wide bandgap small molecular acceptor.adv. mater.2017,29, 1606054. (if = 27.398)
2016年度
1. xiaopeng xu, zuojia li,zhengguowang, kai li, kui feng, and qiang peng.* 10.20% efficiency polymer solar cells via employing bilaterally hole-cascade diazaphenanthrobisthiadiazole polymer donors and electron-cascade indene-c70 bisadduct acceptor.nano energy2016,25, 170. (if = 16.602)
2. xiaopeng xu, kui feng, kai li, qiang peng. synthesis and photovoltaic properties of two-dimensional benzodithiophene-thiophene copolymers with pendent rational naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole side chains.j. mater. chem. a2015,3, 23149.(if = 11.301)
3. xiaopeng xu, ying li, mei-mingluo, andqiang peng.*recent progress towards fluorinated copolymers for efficient photovoltaic applications.chin. chem. lett.2016,27, 1241.(if = 4.632)
4. qunping fan,xiaopeng xu, yu liu, wenyan su, xunming he, youming zhang, hua tan, yafei wang, qiang peng,* weiguo zhu.* enhancing the photovoltaic properties of low bandgap terpolymers based on benzodithiophene and phenanthrophenazine by introducing different second acceptor units.polym. chem.2016,7, 1747. (if = 5.342)
5. zhenguo wang, zuojia li,xiaopeng xu, ying li, kai li,qiang peng.*polymer solar cells exceeding 10% efficiency enabled via a facile star-shaped molecular cathode interlayer with variable counterions.adv. funct. mater.2016,26, 4643.(if =16.836)
6. hongrui qi, youming zhang, qiang tao, jianhua chen, zuojia li,xiaopeng xu, hua tan,qiang peng,*weiguo zhu.*novel d(a-ar)2type small molecules with oligothiophene, diketopyrrolopyrrole and benzo[4,5]thieno[2,3-b]indole units: investigation on relationship between structure and property for organic solar cells.tetrahedron2016,72, 7430. (if = 2.233)
2015年以前
1. xiaopeng xu, kai li,zuojiali, ying li, zhenguo wang, qiang peng.* the enhanced performance of fluorinated quinoxaline-containing polymers by replacing carbon with silicon bridging atoms on the dithiophene donor skeleton.polym. chem.2015,6, 2337.(if = 5.342)
2. ying li,xiaopeng xu, zuojia li, ting yu, qiang peng.* two-dimensional photovoltaic copolymers with spatial d-a-d structures: synthesis, characterization and hetero-atom effect.sci. china chem.2015,58, 276. (if = 6.356)
3. kui feng,xiaopeng xu, zuojia li, ying li, kai li, ting yu and qiang peng.* low band gap benzothiophene-thienothiophene copolymers with conjugated alkylthiothieyl and alkoxycarbonyl cyanovinyl side chains for photovoltaic applications.chem. commun.2015,51, 6290. (if = 5.996)
4. xiaopeng xu, yulei wu, junfeng fang,*zuojia li, zhenguo wang, ying, li, and qiang peng.*side-chain engineering of benzodithiophene-fluorinated quinoxaline low-band-gap copolymers for high-performance polymer solar cells.chem. eur. j.2014,20, 13259.(if = 4.857)
5. yuchong yang, renming wu, xin wang,*xiaopeng xu, zuojia li, kai li and qiang peng.* isoindigo fluorination to enhance photovoltaic performance of donor-acceptor conjugated copolymers.chem. commun.2014,50, 439. (if = 5.996)
6. kai li, zuojia li, kui feng,xiaopeng xu, lingyan wang, and qiang peng.* development of large band-gap conjugated copolymers for efficient regular single and tandem organic solar cells.j. am. chem. soc.2013,135, 13549. (if = 14.612)
发明专利清单:
1.彭强,李作佳,张光军,徐小鹏.一种侧链含高电子迁移率芳杂环的醇/水溶性有机小分子阴极界面材料.中国发明专利(专利申请号:201811017055.8,专利申请日:2018.09.03,授权公告号:cn108947927b,授权公告日:2020.05.26)
2.彭强,武文林,张光军,徐小鹏.一种宽带隙星型非富勒烯小分子受体的制备方法及其应用.中国发明专利(专利申请号:201710878172.2,专利申请日:2017.09.26,授权公告号:cn107602551 b,授权公告日:2020.03.03)